We study the local dynamical fluctuations in glass-forming models of particles embedded in d-dimensional space, in the mean-field limit of d - ???. Our analytical calculation reveals that single-particle observables, such as squared particle displacements, display divergent fluctuations around the dynamical (or mode-coupling) transition, due to the emergence of nontrivial correlations between displacements along different directions. This effect notably gives rise to a divergent non-Gaussian parameter, ??2. The d - ??? local dynamics therefore becomes quite rich upon approaching the glass transition. The finite-d remnant of this phenomenon further provides a long sought-after, first-principle explanation for the growth of ??2 around the glass transition that is not based on multiparticle correlations.

Local Dynamical Heterogeneity in Simple Glass Formers / Biroli, G; Charbonneau, P; Folena, G; Hu, Y; Zamponi, F. - In: PHYSICAL REVIEW LETTERS. - ISSN 0031-9007. - 128:17(2022). [10.1103/PhysRevLett.128.175501]

Local Dynamical Heterogeneity in Simple Glass Formers

Zamponi F
2022

Abstract

We study the local dynamical fluctuations in glass-forming models of particles embedded in d-dimensional space, in the mean-field limit of d - ???. Our analytical calculation reveals that single-particle observables, such as squared particle displacements, display divergent fluctuations around the dynamical (or mode-coupling) transition, due to the emergence of nontrivial correlations between displacements along different directions. This effect notably gives rise to a divergent non-Gaussian parameter, ??2. The d - ??? local dynamics therefore becomes quite rich upon approaching the glass transition. The finite-d remnant of this phenomenon further provides a long sought-after, first-principle explanation for the growth of ??2 around the glass transition that is not based on multiparticle correlations.
2022
Glass transition; fluctuations; statistical mechanics
01 Pubblicazione su rivista::01a Articolo in rivista
Local Dynamical Heterogeneity in Simple Glass Formers / Biroli, G; Charbonneau, P; Folena, G; Hu, Y; Zamponi, F. - In: PHYSICAL REVIEW LETTERS. - ISSN 0031-9007. - 128:17(2022). [10.1103/PhysRevLett.128.175501]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/1693795
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